There are 10 new Trophies in this DLC.

Bronze

Make It Possible
Succeed in a Challenge

One Down
Defeat all teams from a group in Expedition

On All Fronts
Defeat one team from each group in Expedition

National Pride
Win an Expedition match with all starting 11 from the same nation

We Are The Champions
Win UEFA EURO 2012

Creating History Together
Win UEFA EURO 2012 with more than 1 user playing for the same team in all 6 matches[/COLOR]

Glory Moment
Win Online UEFA EURO 2012

Silver

My Euro
Win a match in each UEFA EURO 2012 game mode

Expeditionary Nature
Defeat all 53 Nations in Expedition

Collector
Collect all mosaic peices in Expedition

http://www.ps3trophies.com/forums/playstation-trophy-news/15512-uefa-euro-2012-dlc-trophy-list.html