There are 41 Trophies that can be collected.

Bronze

Training complete
Complete the full tutorial.

TV time for my sponsor
Maintain a solo breakaway for, at least, 20 kms.

Never alone
Use all Team Communication options.

Be my guest
Win a quick match in multiplayer mode.

Attack!!!!!
Launch an attack from the peloton to gain a few metres lead.

I slipped boss!
Fall off the bike while wearing the yellow jersey.

Rider combativity prize
Be on the first breakaway (E1) for at least 500km during the same Tour de France.

125cc
Ride faster than 70 km/h in a flat section.

Moto GP
Ride faster than 90 km/h.

Finally some rest
Reach the first rest day (stage 10: Mâcon).

The most difficult is still to come
Reach the second rest day (stage 17: Pau).

Raise your arms
Your first victory.

Enjoy the victory
Use a celebration combo when you win a stage.

On my own
Win a stage with a solo breakaway (at least the last km).

Faster than you think
Wear the green jersey for at least 1 stage with a silver or bronze sprinter.

King of the hills
Wear the king of mountains jersey from the end of the 2nd stage until the 1st mountain stage (Stage 11: Mâcon).

Fast & furious
Win a flat stage with a gold medal sprinter.

Demolition man
Win a stage with more than 2 minutes advance on the 2nd rider.

Master of alliances
Create 1 alliance in mode Tour de France.

Like father like son
Win a stage with a 30+ rider and with a -25 rider during the same Tour de France.

Champs Elysees
Complete a Tour de France.

Back-to-back
Win 2 consecutive stages with the same rider.

When the going get's tough . . .
Wear the yellow jersey for 7 stages with an Expert level team during the same Tour de France.

All-rounder
Win a stage of each type (Tour or One-off) with any rider of the same team.

On the souvenir photo
Finish the Tour de France in the top 3 (Tour only).

Start and finish
Win the first and last stages of the Tour de France in Tour mode.

Welcome to the club
Win a Tour de France.

King of the mountains
Win the polka-dot jersey.

King of the sprint
Win the green jersey.

King Midas
Accumulate more than 500,000 EUR during a Tour de France

Baby champion
Win the white jersey (tour mode only).

I'm at home in the mountains
Be the first across all Hors Category climbs during the same Tour de France.

Silver

Three in a row
Win 3 consecutive stages with the same rider (Tour mode).

From nowhere
Win a stage with a rider who has no medals (Tour or One-Off).

Monsieur Tour de France
Win at least 5 stages on the same Tour with the same rider (Tour mode only).

Gold

From start to finish
Win the first stage and keep the yellow jersey on the same rider throughout all stages of the Tour de France.

Dream team
Win the Tour de France and have a team-mate on the podium.

Veteran
Win the Tour de France with a Difficult or Expert team.

Tour legend
Win all stages (Tour or One-Off) with the same or different riders.

Son of the Cannibal
Win the Yellow, Green and Polka-dot jerseys on the same edition with the same rider.

Platinum

Champion of champions
Obtain all trophies.

http://www.ps3trophies.com/forums/playstation-trophy-news/19144-tour-de-france-2012-trophy-list.html

tonycawley said
I can't believe they've made a game of the tour de france. This has to be the most boring thing ever, surely? The only interesting thing about the tour is the amazing feat oh human endurance and that can't translate in a game. I'm interested in giving it a go just for the hell of it, its got to be the shittest game ever made.

get the 2011 version if you just want to try it cheaper.