There are 39 Trophies that can be collected.

Bronze

TRAINING COMPLETE
Complete the Tutorial

NOT WITHOUT MY HEADSET
Use all audio communication options

IN CONTROL
Use each of your riders to lead the peloton

SURPRISING ATTACKER
Be the first to attack on a stage

JUST FOR FUN
Win any stage

TV TIME FOR MY SPONSOR
Maintain a solo breakaway for more than 20 km

IF YOU DON'T TRY YOU CAN'T WIN
Unleash at least 10 attacks during the last climb of a mountain stage

I LIVE IN THE MOUNTAINS
Be first on every mountain sprint during a stage ranked Mountain

AVOID RISKS
Win the Tour de France without falling from the bike

MASTER MIND
Set up an alliance with the peloton and in a breakaway in the same stage and win the stage

FAST AS THE WIND
Escape from the peloton, going downhill, and gain a 30 seconds lead

DON'T LET ME DOWN
Help a team leader, who has fallen behind, return to the peloton (playing as leader or team-mate)

MAN OF HIS WORD
Let a rider who helped you in an alliance win the stage

STRONG FINISHER
Win a flat stage with a non-sprinter arriving in the peloton

BACK-TO-BACK
Win 2 consecutive stages with the same rider

FAST GUY
Win a flat stage with a sprinter

NO PREFERENCES
Complete a Tour de France with every team in the game

CLIMB LIKE AN ANGEL
Win all the mountain stages of a Tour de France (Tour mode)

KING OF THE MOUNTAINS
Win the polka-dot jersey

KING OF THE SPRINTS
Win the green jersey

BRITISH PUNCTUALITY
Win the Individual Time-Trial and then beat your time the next time you play

NEVER TOO YOUNG FOR YELLOW
Win the Tour de France with a rider aged 25 or under

USUAL SUSPECTS
Finish in the Top 10 in at least 5 consecutive Tour de France

FIRST AND LAST
Win the first and last stages of the Tour de France in Tour mode

UNDERDOG
Win the Tour de France with a rider who is not the best ranked rider in his team

FRENCH SKILLS
Win a stage with a team of Expert difficulty

ALLROUNDER
Win a stage of each type (Flat, Hills, Mountain, Time-trial) with the same rider

THREE IN A ROW
Win 3 consecutive stages with the same rider (Tour mode)

Silver

THE SMALL TEAMS COUNT TOO
Finish in the top 10 in the General Ranking with a team of Expert difficulty

NEVER SAY NEVER
Win the Tour de France after clawing back a 10 minute deficit with the leader

ALL FOR MY TEAM-MATES
Win a stage with a rider you don't control by making him attack

FROM START TO FINISH
Wear the yellow jersey on all the stages of the Tour de France

ALWAYS ON TIME
Win all the intermediary sprints of the Tour de France (Tour mode)

AMONGST THE GODS
Win at least 2 Tour de France

Gold

EXPERIENCED PLAYER
Win the Tour de France with a Beginner, Intermediate, Hard and Expert team

TOUR LEGEND
Win at least 5 Tour de France

SON OF THE CANNIBAL
Win the Yellow, Polka-dot and Green jersey on the same edition with the same

ABSOLUTE DOMINATION
Have your team win all the stages of the Tour de France and all 3 leader jerseys

Platinum

MR TOUR DE FRANCE
Obtain all trophies

http://www.ps3trophies.com/forums/ps3-trophy-news/63933-tour-de-france-official-game-trophy-list.html