There are 14 Trophies that can be collected.

BRONZE

Last Mage Standing
Win a 3-player, 4-player, or Two-Headed Giant duel

Two-Headed Giant
Win a Two-Headed Giant duel

Maelstrom Wanderer
Win a Planechase campaign duel

Otherworldly Journey
Win a duel online

Praetor Slayer
Solve the Say Your Praetors challenge in all five ways

Flawless
Win a campaign duel with 20 or more life

Savor the Moment
Win a campaign duel with an opponent's library empty

Master of the Wild Hunt
Win a duel controlling at least ten creatures

Beast Within
Win a duel controlling a creature with at least 10 power

Fearless Explorer
Defeat ten encounters

Challenge Master
Solve ten challenges

SILVER

Jack of All Trades
Unlock a card for each of ten different decks

Archmage
Unlock 30 cards for one deck

GOLD

Dragon Slayer
Defeat Nicol Bolas in the revenge campaign

http://www.ps3trophies.com/forums/playstation-trophy-news/18362-magic-gathering-duels-planeswalkers-2013-trophy-list.html

Mundham said

As always, thanks Skib

thanks mate.